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Bismuth Borate Crystal | BIBO Crystal

HM2820

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Bismuth Borate (BIBO) Crystal is a newly developed nonlinear optical crystal with a highly effective nonlinear optical coefficient, high damage threshold, and resistance to deliquescence. It is an excellent frequency-doubling crystal, particularly for blue laser generation. Heeger Materials is a professional supplier and manufacturer of high-quality BIBO crystal, offering customized solutions.

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Data sheet

Density5.033 g/cm³
MaterialsBIBO
Melting Piont726 ℃
Molecular FormulaBiB3O6

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Bismuth Borate (BIBO) Crystal is a high-performance nonlinear optical material, known for its large effective nonlinear optical coefficient, which is 3.5-4 times higher than LBO crystals and 1.5-2 times higher than BBO crystals. It also boasts a high damage threshold and excellent resistance to deliquescence, making it ideal for use in harsh environments. BIBO crystals are highly effective in frequency doubling applications, especially for blue laser generation, offering significant advantages over other nonlinear crystals. Heeger Materials (HM) provides high-quality Bismuth Borate (BIBO) crystals for advanced laser and nonlinear optical applications.

Bismuth Borate Crystal | BIBO Crystal

Bismuth Borate Crystal Specifications

Size Tolerance

(W±0.1 mm) × (H±0.1 mm) × (L+0.5/-0.1 mm) (L≥2.5 mm) 

(W±0.1 mm) × (H±0.1 mm) × (L+0.1/-0.1 mm) (L<2.5 mm)

Effective Aperture

90% Central Area

Surface Quality

10/5 Referencing MIL-PRF-13830B Standard

Flatness

λ/8 @ 633 nm

Transmitted Wavefront Distortion

λ/8 @ 633 nm

Parallelism

20″

Perpendicularity

≤15′

Angle Tolerance

Δθ≦0.25°, ΔФ≦0.25°

Edge Chips

≦0.1 mm

Chamfer

≦0.2 mm×45°

Damage Threshold

>0.3 GW/cm² @ 1064 nm, 10 ns, 10 Hz (Anti-Reflective Coating)

Bismuth Borate Crystal Chemical and Structural Properties

Crystal Structure

Monoclinic System, Point Group C2-2

Unit Cell Parameters

a = 7.116 Å, b = 4.993 Å, c = 6.508 Å, β = 105.62°, Z = 2

Melting Point

726 ℃

Mohs Hardness

5-5.5 Mohs

Density

5.033 g/cm³

Thermal Expansion Coefficient

αa = 4.8×10⁻⁵ /K, αb = 4.4×10⁻⁶ /K, αc = -2.69×10⁻⁵ /K

Bismuth Borate Crystal Optical and Nonlinear Optical Properties

Transmission Band

286-2500 nm

Absorption Coefficient

<0.1%/cm @ 1064 nm

Physical Axis

X∥b, (Z, a) = 31.6°, (Y, c) = 47.2°

1064/532 nm Second Harmonic Generation (SHG)

Phase-Matching Angle

Angle with Z-axis 168.9°, YZ Plane

Coefficient

3.0±0.1 pm/V

Acceptance Angle

2.32 mrad•cm

Walk-off Angle

25.6 mrad

Temperature Bandwidth

2.17 ℃•cm

Sellmeier Coefficient

n2i(λ) = A + B/(λ² - C) - Dλ² (λ unit µm)

 

A

B

C

D

n1

3.6545(4)

0.0511(2)

0.0371(3)

0.0226(1)

n2

3.0740(3)

0.0323(1)

0.0316(3)

0.01337(6)

n3

3.1685(3)

0.0373(1)

0.0346(3)

0.01750(8)

Bismuth Borate Crystal Coating

  • Coatings can be applied for BIBO crystal's second and third harmonic generation with dual-wavelength and triple-wavelength antireflection coatings.
  • Coatings can be applied for wideband antireflection coatings (BBAR-coating) or protective coatings (P-coating) for BIBO-OPO systems.
  • Low reflectance.
  • Long lifespan.
  • Custom coating services are available.

Bismuth Borate Crystal Key Advantages

  • High laser damage threshold
  • Large nonlinear optical coefficient
  • Stable physical and chemical properties

Bismuth Borate Crystal Applications

  • Frequency Doubling for Nd: YAG Lasers: BIBO crystals are used for frequency doubling of Nd: YAG lasers, including at 946 nm, to generate higher-frequency outputs.
  • Frequency Generation for Nd: YVO4 Lasers: BIBO crystals are used for generating 593.5 nm by frequency conversion of Nd: YVO4 lasers at 1064 nm and 1342 nm.
  • Optical Parametric Oscillators (OPO): BIBO is an effective nonlinear crystal for optical parametric oscillators, providing tunable wavelengths in various applications.
  • Blue Light Generation: BIBO crystals are ideal for generating blue light through frequency doubling, making them suitable for blue laser applications.
  • High-Efficiency Frequency Conversion: BIBO is used in high-efficiency frequency conversion processes, including second and third harmonic generation, due to its high nonlinear optical coefficient.

Bismuth Borate Crystal Packing And Shipping

Bismuth Borate (BIBO) Crystal will be securely packaged in sturdy containers with cushioning materials to prevent movement or damage during shipping. This careful packaging ensures that the product arrives in perfect condition, maintaining its high-quality standards throughout the delivery process.

Bismuth Borate Crystal | BIBO Crystal Packing

Where to Buy Bismuth Borate Crystal in Bulk?

Heeger Materials Inc., a professional supplier and manufacturer of high-quality Nonlinear Crystals products including Bismuth Borate (BIBO) Crystal, leverages extensive expertise in supply and export to offer competitive prices. We provide customized solutions to meet specific requirements, ensuring exceptional quality and customer satisfaction.

Heeger Materials Inc. was established in 2016 in Colorado, USA. We specialize in premium-grade metals, alloys, ceramics, powders, and other materials catering to research, development, and large-scale industrial production in scientific and industrial sectors. 

Nonlinear Crystal Stock Models

Nonlinear Crystal Type

BBO, ß-BaB₂O₄

KTP, KTiOPO₃

LBO, LiB₃O₅

BIBO, BiB₃O₆

CLBO, CsLiB₆O₁₀

Transmission Range (nm)

190-3500

350-4500

160-2600

286-2500

180-2750

SHG Phase-Matching Range (nm)

409.6-3500 (Type I)

25-3500

(Type II)

994-2000 (Type II)

551-2600 (Type I)

790-2150 (Type II)

574-2480

473-2750 (Type I) 636-2750 (Type II)

Effective Nonlinear Coefficient deff SHG 1064 nm [pm/V]

2.14 (Type I)

1.47 (Type II)

4.03 (Type II)

0.82 (Type I)

3.34

0.9 (Type I, 4HG)  1.19 (Type I, 5HG) 0.95 (Type II)

Absorption Coefficient [%/cm]

<0.1@1064nm <1@532nm

<0.1@1064nm <1@532nm

<0.1@1064nm <0.3@532nm

<0.1@1064nm

<0.03@1064nm <0.1@532nm

Acceptance Angle SHG 1064 nm [mrad/cm]

0.8 (Type I)  1.27 (Type II)

14.2 (φ)

55.3 (θ)

6.54 (Type I)  15.27 (Type II)

1.03 (ee-o)

 0.45 (Type I, 4HG)

0.42 (Type I, 5HG)

1.90 (Type II)

Walk-off Angle SHG 1064 nm [mrad]

55.6 (Type I)  69.4 (Type II)

4.87 (Type II)

6.7 (Type I)

6.4 (Type II)

24.5 (Type I)

7.85 (Type I, 4HG)

7.33 (Type I, 5HG)

33.1 (Type II)

Acceptance Temperature SHG 1064 nm [°C/cm]

70

24

6.7 (Type I) 7.5 (Type II)

2.17

8.30 (Type I, 4HG)

4.60 (Type I, 5HG)

43.1 (Type II)

Acceptance Spectrum

1.1

0.56

1.0 (Type I)

1.3 (Type II)

0.96 (ee-o)

 0.13 (Type I, 4HG)

0.16 (Type I, 5HG)

5.60 (Type II)

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