Instruction for use of evaporation materials

Instruction for use of evaporation materials

In various fields of science and engineering, evaporation materials play a crucial role. Whether it's thin-film deposition in materials science or vacuum evaporation in chemical engineering, evaporation materials are essential components for various applications and research endeavors. To ensure the accuracy and success of experiments, the correct selection and utilization of evaporation materials.

What is evaporation material?

Evaporation materials refer to substances used in the process of evaporation to deposit thin films or coat surfaces. They typically possess high purity and specific chemical properties to ensure that the resulting films have the desired performance and characteristics. The choice of evaporation materials depends on specific application requirements, including but not limited to optical coatings, electronic devices, solar cells, and coating technologies.

The classification of evaporation material

Metallic and Non-metallic pellet

Aluminum (Al) Evaporation Material

Nickel (Ni) Evaporation Material

Copper (Cu) Evaporation Material

Titanium (Ti) Evaporation Material

Vanadium (V) Evaporation Material

Indium (In) Evaporation Material

Tin (Sn) Evaporation Material

Chromium (Cr) Evaporation Material

Cerium (Ce) Evaporation Material

Silicon (Si) Evaporation Material

Boron (B) Evaporation Material, etc.

Oxide

Zirconium Oxide (ZrO2) Evaporation Material

Aluminum Oxide (Al2O3) Evaporation Material

Titanium Pentoxide (Ti3O5) Evaporation Material

Antimony Oxide (Sb2O3) Evaporation Material

Bismuth Oxide (Bi2O3) Evaporation Material

Cerium Oxide (CeO2) Evaporation Material

Chromic Oxide (Cr2O3) Evaporation Material

Gadolinium Oxide (Gd2O3) Evaporation Material

Hafnium Oxide (HfO2) Evaporation Material

Indium Oxide (In2O3) Evaporation Material

Praseodymium Oxide (Pr6O11) Evaporation Material, etc.

Fluoride

Cerium Fluoride (CeF3) Evaporation Material

Dysprosium Fluoride (DyF3) Evaporation Material

Lanthanum Fluoride (LaF3) Evaporation Material

Magnesium Fluoride (MgF2) Evaporation Material, etc.

Carbide

Hafnium Carbide (HfC) Evaporation Material

Silicon Carbide (SiC) Evaporation Material

Boron Carbide (B4C) Evaporation Material, etc.

Sulfide

Copper Sulfide (CuS) Evaporation Material

Zinc Sulfide (ZnS) Evaporation Material

Cadmium Sulfide (CdS) Evaporation Material, etc.

Nitride

<Silicon Nitride (Si3N4) Evaporation Material

Titanium Nitride (TiN) Evaporation Material

Aluminum Nitride (AlN) Evaporation Material

Boron Nitride (BN) Evaporation Material, etc.

Selenide

Zinc Selenide (ZnSe) Evaporation Material

Aluminium Selenide (Al2Se3) Evaporation Material

Arsenic triselenide (As2Se3) Evaporation Material, etc.

Telluride

Silver telluride (Ag2Te) Evaporation Material

Aluminum Telluride (Al2Te3) Evaporation Material

Bismuth Telluride (Bi2Te3) Evaporation Material, etc.

Arsenide

Lead Arsenic (PbAs) Evaporation Material

Tin Arsenic (SnAs) Evaporation Material

Zinc Arsenic (ZnAs) Evaporation Material

Antimonide

Aluminium Antimony (AlSb) Evaporation Material

Cadmium Antimony (CdSb) Evaporation Material

Indium Antimony (InSb) Evaporation Material, etc.

The forms of evaporation material

Evaporation materials come in various forms, including blocks, foils, granules, wires, rods, tablets, and pellets.

How do you choose appropriate evaporation materials?

  • Application Requirements: Determine the specific application for thin film deposition, such as optical coatings, electronic devices, or solar cells.
  • Melting point: The material should have a melting point higher than the required evaporation temperature.
  • Saturated vapor pressure: The material should have an appropriate saturated vapor pressure to evaporate at the desired temperature.
  • Chemical stability: The material should remain chemically stable and not react with other elements or compounds.
  • Physical form: Choose the appropriate physical form, such as granule, rod, or pellet, according to the requirements of the evaporation equipment.
  • Purity: Materials with high purity can reduce impurities and improve the quality of the film.
  • Economy: Consider cost-effectiveness and choose evaporation materials that offer good value for money.

How do you choose the right crucible for evaporation materials?

  • High melting point materials (evaporation source material melting point > evaporation temperature).
  • Reduce contamination of the evaporation source (the evaporation temperature of the film material is < the temperature corresponding to the evaporation source material at a vapor pressure of 10-8 Torr).
  • The evaporation source material does not react with the film material.
  • Wetting of the evaporation source material by the film material.
  • Commonly used evaporation source materials include iridium crucibles, tungsten crucibles, molybdenum crucibles, tantalum crucibles, high-temperature resistant metal oxides, ceramics, or graphite crucibles.

What are the precautions in the use of evaporative materials?

  • Crucible selection: Choose a crucible that is compatible with the evaporative material, ensuring it can withstand high temperatures and will not react chemically with the evaporative material.
  • Cleaning and pretreatment: Maintain the cleanliness of the crucible and perform proper pretreatment before use to reduce contamination and impurities' impact on experimental results.
  • Material loading: Use appropriate loading techniques to evenly place the evaporative material in the crucible, avoiding uneven evaporation and deposition.
  • Temperature control: Precisely control the temperature during the evaporation process to ensure a stable evaporation rate and film quality.
  • Humidity management: When using evaporation materials in high-humidity environments, control the humidity to prevent condensation and mold growth.
  • Vacuum conditions: Create an appropriate vacuum environment to minimize the influence of gases and impurities on the evaporation process and deposited films.
  • Safe operation: Follow safety protocols, including wearing protective equipment and handling hazardous materials properly, to ensure the safety of experimenters.

Sputtering and evaporation are the two main PVD coating methods. Sputtering offers good repeatability and controllable film thickness, suitable for large-area substrates. Evaporation is simpler, convenient, and faster, commonly used for coating small-sized substrates.

Future evaporation materials will be more efficient and eco-friendly. As technology advances, they will drive progress in industries like optoelectronics and solar energy, while reducing energy and waste in production.

Click to download Comprehensive Guide to Evaporative Materials: Properties, Procedures, and Recommendations